The UPSC Chemistry Paper II Syllabus focuses on topics like Delocalised covalent bonding, Reaction mechanisms, Pericyclic reactions, Preparation and Properties of Polymers, Synthetic Uses of Reagents, Photochemistry, Spectroscopy, etc. Lanthanides and actinides: separation, oxidation states, magnetic and spectral properties lanthanide contraction. (iv) Complexes with aromatic systems, synthesis, structure and bonding in metal olefin complexes, alkyne complexes and cyclopentadienyl complexes coordinative unsaturation, oxidative addition reactions, insertion reactions, fluxional molecules and their characterization Compounds with metal-metal bonds and metal atom clusters.īoranes, borazines, phosphazenes and cyclic phosphazene, silicates and silicones, Interhalogen compounds Sulphur-nitrogen compounds, noble gas compounds. (iii) EAN rule, Synthesis structure and reactivity of metal carbonyls carboxylate anions, carbonyl hydrides and metal nitrosyl compounds. (ii) Isomerism in coordination compounds IUPAC nomenclature of coordination compounds stereochemistry of complexes with 4 and 6 coordination numbers chelate effect and polynuclear complexes trans effect and its theories kinetics of substitution reactions in square-planar complexes thermodynamic and kinetic stability of complexes. Valence bond theory, crystal field theory and its modifications applications of theories in the explanation of magnetism and elctronic spectra of metal complexes. (i) Bonding in transition of metal complexes. Metal ions in biological systems and their role in ion-transport across the membranes (molecular mechanism), oxygen-uptake proteins, cytochromes and ferrodoxins. adsorption isotherms determination of surface area, characteristics and mechanism of reaction on heterogeneous catalysts. Collisions and transition state theories.Ībsorption of light decay of excited state by different routes photochemical reactions between hydrogen and halogens and their quantum yields.Īdsorption from gases and solutions on solid adsorbents Langmuir and B.E.T. Study of fast reactions by stop-flow and relaxation methods. Processes at electrodes double layer at the interface rate of charge transfer, current density overpotential electroanalytical techniques : amperometry, ion selective electrodes and their use.ĭifferential and integral rate equations for zeroth, first, second and fractional order reactions Rate equations involving reverse, parallel, consecutive and chain reactions Branching chain and explosions effect of temperature and pressure on rate constant. of cells and its applications fuel cells and batteries. Ionic bond, characteristics of ionic compounds, lattice energy, Born-Haber cycle covalent bond and its general characteristics, polarities of bonds in molecules and their dipole moments Valence bond theory, concept of resonance and resonance energy Molecular orbital theory (LCAO method) bonding H2 +, H2 He2 + to Ne2, NO, CO, HF, CN–, Comparison of valence bond and molecular orbital theories, bond order, bond strength and bond length.ĭebye-Huckel theory of strong electrolytes and Debye-Huckel limiting Law for various equilibrium and transport properties.Galvanic cells, concentration cells electrochemical series, measurement of e.m.f. Heisenberg's uncertainty principle Schrodinger wave equation (time independent) Interpretation of wave function, particle in one- dimensional box, quantum numbers, hydrogen atom wave functions Shapes of s, p and d orbitals. Check the topic-wise UPSC Chemistry Optional Syllabus for Paper I below. The UPSC Chemistry Paper I syllabus covers topics like Atomic Structure, Chemical bonding, Solid state, Phase equilibria and solutions, The gaseous state and Transport Phenomenon, Thermodynamics, Liquid State, etc.
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